They do so in a one-step process at temperatures low enough to make graphene easy to manufacture.
The lab of Rice University chemist James Tour reports in the journal Nature this week that large-area, high-quality graphene can be grown from a number of carbon sources at temperatures as low as 800 degrees Celsius (1,472 F). As hot as that may seem, the difference between running a furnace at 800 and 1,000 degrees Celsius is significant, Tour says.
“At 800 degrees, the underlying silicon remains active for electronics, whereas at 1,000 degrees, it loses its critical dopants,” says Tour.
Zhengzong Sun, a graduate student in Tour’s lab and primary author of the paper, found that depositing carbon-rich sources on copper and nickel substrates produced graphene in any form he desired: single-, bi-, or multilayer sheets that could be highly useful in a number of applications.
Sun and his colleagues also found the process adapts easily to producing doped graphene; this allows the manipulation of the material’s electronic and optical properties, which is important for making switching and logic devices.
For pristine graphene, Sun started with a thin film of poly (methyl methacrylate) (PMMA)—perhaps best known in its commercial guise as Plexiglas—spun onto a copper substrate that acted as a catalyst. Under heat and low pressure, flowing hydrogen and argon gas over the PMMA for 10 minutes reduced it to pure carbon and turned the film into a single layer of graphene. Changing the gas-flow rate allowed him to control the thickness of the PMMA-derived graphene.
Then it got more interesting, Sun says. He turned to other carbon sources, including a fine powder of sucrose—aka table sugar. “We thought it would be interesting to try this stuff,” Sun says. “While other labs were changing the metal catalysts, we tried changing the carbon sources.”
Sun put 10 milligrams of sugar (and later fluorene) on a square-centimeter sheet of copper foil and subjected it to the same reactor conditions as the PMMA. It was quickly transformed into single-layer graphene. Sun had expected defects in the final product, given the chemical properties of both substances (a high concentration of oxygen in sucrose, five-atom rings in fluorene); but he found potential topological defects would self-heal as the graphene formed.
“As we looked deeper and deeper into the process, we found it was not only interesting, but useful,” Sun says.
He tried and failed to grow graphene on silicon and silicon oxide, which raised the possibility of growing patterned graphene from a thin film of shaped copper or nickel deposited onto silicon wafers.
Doped graphene opens more possibilities for electronics use, Tour says, and Sun found it fairly simple to make. Starting with PMMA mixed with a doping reagent, melamine, he discovered that flowing the gas under atmospheric pressure produced nitrogen-doped graphene.
Pristine graphene has no bandgap, but doped graphene allows control of the electrical structure, which the team proved by building field-effect transistors.
“Each day, the growth of graphene on silicon is approaching industrial-level readiness, and this work takes it an important step further,” Tour says.
The Air Force Office of Scientific Research and the Office of Naval Research supported the work.
Source: Rice University